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Flash photolysis of N-acetyl-L-tryptophanamide; evidence for radical production without hydrated electron formation

✍ Scribed by R.F. Evans; C.A. Ghiron; W.A. Volkert; R.R. Kuntz; R. Santus; M. Bazin

Publisher: Elsevier Science
Year: 1976
Tongue: English
Weight: 376 KB
Volume: 42
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(76)80546-5

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✦ Synopsis

Electron countmg methods show that approximately 50% of the neutral r2dlcals produced m the flash photolysis of N-acetyl-L-tryptophanamide (NATA) are not accompanied by hydrated electron formation. Thus, the rzeutral radical cannot or&ate solely from the photoionlzatlon reaction.

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Flash photolysis of N-acetyl-L-tryptopha

Flash photolysis of N-acetyl-L-tryptophanamide; proton quenching of radical and electron production

✍ R.F. Evans; C.A. Ghiron; R.R. Kuntz; W.A. Volkert 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 416 KB

Proton quenching of fluorescence, radical and electron production in the flash photorysis of N-acetyl-L-tryptophanamide indicates these processes originate from a common state. An indole photolysis model consistent with these and carlier observations is suggested.