Flash photolysis of aqueous solutions of bis(μ-oxo) bis(oxo-molybdenum(V))
✍ Scribed by Mónica C. Gonzalez; Mario R. Féliz; Enrique San Román; Alberto L. Capparelli
- Book ID
- 103993380
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 784 KB
- Volume
- 48
- Category
- Article
- ISSN
- 1010-6030
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The flash photolysis of di-p-oxo his(oxo-molybdenum(V)) complexes in aqueous solutions of perchloric acid in the presence of excess chloride induced both photolabilization and photo-oxidation of Cl-and/or H,O ligands. Photolabilization produces the formation of reaction intermediates identified as
## Abstract The flash photolysis of the mono and di‐thiocyanate complexes of μ‐oxo __bis__(oxo‐molybdenum(V)) (Mo~2~O~4~(NCS)~__x__~(H~2~O)~6−__x__~^(2−__x__)+^ where __x__ = 1, 2) has been studied in the system composed of perchloric acid solutions of Mo~2~O~4~(H~2~O)~6~^2+^ in the presence of exc