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Flash Photolysis Observation and Lifetimes of 2-Fluorenyl- and 4-Biphenylylacetylnitrenium Ions in Aqueous Solution

✍ Scribed by Davidse, P. Adriaan; Kahley, Mary Jo; McClelland, Robert A.; Novak, Michael


Book ID
126878658
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
261 KB
Volume
116
Category
Article
ISSN
0002-7863

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## Abstract 5‐Methyl‐1,4‐naphthoquinone (1) is a remarkable probe to study hydrogen and proton transfer reactions. The photoenol 4‐hydroxy‐5‐methylidene naphthalen‐1 (5__H__)‐one (2) is formed in the ground state within 2 ps of excitation and with a quantum yield of unity, presumably through a coni