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Flame inhibition with electron attachment as the first step

✍ Scribed by Robert M. Mills

Publisher: Elsevier Science
Year: 1968
Tongue: English
Weight: 437 KB
Volume: 12
Category: Article
ISSN: 0010-2180
DOI: 10.1016/0010-2180(68)90068-0

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✦ Synopsis

The sugsestion is made that combustion inhibitio.-, of the type observed with the use of most halogenated hydroca rbons is due to a two-s~p process: ( 1 ) negative ions and free radicals are formed by dissociative electron attachment with the inhibitor molecules, and then (2) these negative ions and/or free radicals react with the free radicals found in • flames. Considerable evidence from the literatur -. is presented which supports this idea. It is concluded that, while the evidence is not conclusive, 3 serious consideration of the idea isiustified.

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