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Fixed-frequency and threshold molecular photoelectron spectra of S 1s, Si 1s and Cl 1s core levels

✍ Scribed by A.W. Potts; H.F. Fhadil; J.M. Benson; I.H. Hillier

Book ID: 103033880
Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 359 KB
Volume: 230
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(94)01206-7

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✦ Synopsis

Fixed-frequency and threshold photoelectron spectra have been recorded for ionization from the S 1s shells in SFer CS2 and COS, the Si 1s shells in SiH4 and Sic& and the Cl 1s shell in SiCl, using synchrotron radiation. Fixed-frequency spectra generally showed a single strong ionization feature with associated weak satellite structure due to excited ionized states. Threshold spectra closely resembled X-ray absorption spectra but with an additional feature due to direct ionization. In cases where resonant process enhanced the NEXAFS spectrum direct ionization was not observed.

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