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Fixation of Atmospheric Carbonyl Compounds by Sodium Bisulfite

โœ Scribed by Wilson, K. W.


Book ID
126840399
Publisher
American Chemical Society
Year
1958
Tongue
English
Weight
429 KB
Volume
30
Category
Article
ISSN
0003-2700

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The reduction of ketones and some esters by sodium borohydride is dramatically accelerated by uv irradiation. The reaction seems to proceed from the (n, .rr\*) excited state of the carbonyl compound. The photocatalytic effect is dependent on the solvent polarity and substituents on aromatic carboxyl