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Five-co-ordinate rhenium thiolato-complexes: the preparations and structures of [ReO(SPh)4]−, [Re(SPh)3(MeCN)(PPh3)] and [Re(NPPh3)(SPh)4]

✍ Scribed by Jonathan R. Dilworth; Bryan D. Neaves; John P. Hutchinson; Jon A. Zubieta

Book ID: 104138987
Publisher: Elsevier Science
Year: 1982
Tongue: English
Weight: 167 KB
Volume: 65
Category: Article
ISSN: 0020-1693
DOI: 10.1016/s0020-1693(00)93554-0

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✦ Synopsis

Although there has been intense recent interest in the chemistry of molybdenum and to some extent, tungsten, with sulphur hgands, elements in Groups V and VII have received scant attention. As part of our studies of the binding characteristics of sulphurligated metal ions [l] we have prepared the first examples of rhemum complexes of monodentate throlates. A series of oxo-dithiolato-complexes of technetium and rhenium were described recently

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