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Five- and six-membered spirocyclic cyclotriphosphazene derivatives with methacryloyl substituents on the spirocyclic ring

✍ Scribed by Robert F. Hayes; Christopher W. Allen

Publisher: John Wiley and Sons
Year: 1998
Tongue: English
Weight: 238 KB
Volume: 9
Category: Article
ISSN: 1042-7163
DOI: 10.1002/(sici)1098-1071(1998)9:7<669::aid-hc12>3.0.co;2-3

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✦ Synopsis

Synthetic procedures have been developed for the preparation of spiro(2,3-dioxypropylmethacryloyltetrachlorcyclotriphosphazene, N 3 P 3 Cl 4 -[OCH 2 CH(OC(O)‫ס‬CH 2 )O] (2) and spiro((2-methyl-3-oxy-2-(oxymethyl)propyl)methacryloyltetrachlorocyclotriphosphazene, N 3 P 3 Cl 4 [OCH 2 CMe(CH 2 OC-(O)‫ס‬CH 2 )CH 2 O] ( ). The 1 H, 13 C and 31 P NMR spectra have been analyzed using two-dimensional (COSY and HETCOR) techniques and spectra simulation methods. The crystal and molecular structure of 3 has been investigated by single-crystal X-ray diffraction techniques. The crystals are monoclinic with the space group P2 1 /C with a ‫ס‬ 12. 154(5), b ‫ס‬ 7.825(5), and c ‫ס‬ 20.208(10) A ˚and b ‫ס‬ 103.240Њ with V ‫ס‬

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