Five- and Six-Coordinate Nitrogen in Azaborane Clusters

✍ Scribed by Peter Paetzold

• Book ID: 102657710
• Publisher: John Wiley and Sons
• Year: 1998
• Tongue: English
• Weight: 838 KB
• Volume: 1998
• Category: Article
• ISSN: 1434-1948
• DOI: 10.1002/(sici)1099-0682(199802)1998:2<143::aid-ejic143>3.0.co;2-4

✦ Synopsis

In the majority of known azaboranes N a B b H c and their deriv-NB 11 H 12 and in their derivatives, however, the nitrogen atoms are 5-or 6-coordinate and thus represent a novel bon-atives, the coordination number of the nitrogen atoms within the cluster does not exceed the classical values of 3 or 4. In ding situation. The synthesis, structure, and reactivity of these azaboranes are reviewed in this article. the azaboranes closo-NB 9 H 10 , nido-NB 10 H 13 , and closo-MICROREVIEWS: This feature introduces the readers to the authors' research through a concise overview of the selected topic. Reference to important work from others in the field is included.