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Five- and Six-Coordinate Nickel(II) Complexes of New Multidentate Ligands Containing 2,9-Disubstituted-1,10-Phenanthroline and Pyrazolyl Units

โœ Scribed by Masood, Md. Athar; Hodgson, Derek J.


Book ID
126429539
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
603 KB
Volume
33
Category
Article
ISSN
0020-1669

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## Reactions of bis(1-oxopyridine-2-thione) Ni II or CH ll with 2,2'-bipyridine (bipy) or 1,10-phenanthroline (phen) yield complexes of stoichiometry: Ni(CsH4NOS)2L {L = bipy, two isomers: (1) and (2), L = phen, one isomer (3)} and Cu(CsH4NOS)2(phen).0.75CHC13 (4). The spectroscopy (i.r., u.v.-vis