Fisher information and kinetic energy functionals: A dequantization approach
β Scribed by I.P. Hamilton; Ricardo A. Mosna
- Book ID
- 104006700
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 558 KB
- Volume
- 233
- Category
- Article
- ISSN
- 0377-0427
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β¦ Synopsis
We strengthen the connection between information theory and quantum-mechanical systems using a recently developed dequantization procedure whereby quantum fluctuations latent in the quantum momentum are suppressed. The dequantization procedure results in a decomposition of the quantum kinetic energy as the sum of a classical term and a purely quantum term. The purely quantum term, which results from the quantum fluctuations, is essentially identical to the Fisher information. The classical term is complementary to the Fisher information and, in this sense, it plays a role analogous to that of the Shannon entropy. We demonstrate the kinetic energy decomposition for both stationary and nonstationary states and employ it to shed light on the nature of kinetic energy functionals.
π SIMILAR VOLUMES
The general characteristics of two-body density functionals TBDF are explored and two new correlation energy functionals are derived using the correlation factor approach. The optimization of the parameters entering the above functionals requires exact and accurate Ε½ . atomic correlation energies AC