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First Total Synthesis of the Sex Pheromone of the Oleander Scale Aspidiotus nerii: An Unusual Sesquiterpenic Functionalized Cyclobutane

✍ Scribed by Inés Petschen; Alfredo Parrilla; M. Pilar Bosch; Cristina Amela; Ana A. Botar; Francisco Camps; Angel Guerrero


Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
208 KB
Volume
5
Category
Article
ISSN
0947-6539

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Syntheses of Cyclobutane Derivatives: To
✍ François-Didier Boyer; Paul-Henri Ducrot 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 374 KB

Synthesis of both enantiomers of the Aspidiotus nerii sex asymmetric centers. Stereoselective synthesis of a number of other trisubstituted cyclobutane derivatives also proves the pheromone and their diastereomers has been achieved using, as a key step, an intramolecular ester enolate versatility of