✦ LIBER ✦

First total synthesis of strobilurin B

✍ Scribed by Marius Sutter

Book ID: 104233025
Publisher: Elsevier Science
Year: 1989
Tongue: French
Weight: 208 KB
Volume: 30
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)80582-7

No coin nor oath required. For personal study only.

✦ Synopsis

A general approach to the synthesis of all known strobilurins -a class of natural products -is outlined with strobilurin B as an example.

Strobilurin A (1) was first isolated in 1969 under the name of mucidin by Musilek and co-workers 1) from the fungus Oudemansiella mucida. The structure as well as a total synthesis of this compound was disclosed in a patent by the same authors 2) . Independently, Anke, Steglich and co-workers discovered strobilurin A (1) and B (2) in a culture of Strobilurinus tenacellus 3) . The

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