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First Total Synthesis of Longimicin D

✍ Scribed by Hiroaki Tominaga; Naoyoshi Maezaki; Minori Yanai; Naoto Kojima; Daisuke Urabe; Risa Ueki; Tetsuaki Tanaka

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
166 KB
Volume
2006
Category
Article
ISSN
1434-193X

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## Abstract For Abstract see ChemInform Abstract in Full Text.

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The synthesis of roquefortine D (1), an alkaloid isolated from the cultures of Penicillium roqueforti, is described. The absolute stereochemistry of the natural product was determined by comparison of its optical rotation with that of the synthetic product. A photo-cleavable o-nitrobenzyl group was