First Total Synthesis and Stereochemical Definition of Isodomoic Acid G.
β Scribed by Yike Ni; Kande K. D. Amarasinghe; Bashar Ksebati; John Montgomery
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 56 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
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## Abstract A stereoselective convergent total synthesis of two acetylenic acids, gallicynoic acid G (**1**) and H (**2**), is reported, involving asymmetric reduction of alkynones **3** and **4**, respectively, with the __Coreyο£Ώ Bakshiο£ΏSibata__ (__CBS__) catalyst as a key step (__Schemeβ 3__), **3*
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