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First synthesis of 5-(1-ethoxyethoxy)-N-methyl-N-phenylthiophen-2-amine and its unexpected alcoholysis

โœ Scribed by O. A. Tarasova; N. A. Nedolya; A. I. Albanov; L. Brandsma; B. A. Trofimov


Book ID
111465064
Publisher
SP MAIK Nauka/Interperiodica
Year
2009
Tongue
English
Weight
176 KB
Volume
45
Category
Article
ISSN
1070-4280

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Cyanation of bis(4,5-dicyano-l-methyl-2-imidazolyl)arnine(1) using cyanogen chloride gave N,N-bis(4,5-dicyano-l-methyl-2-imidazolyl)cyanamide(3) as a light yellow solid. Compound 3 is themmlly labile and upon heating the N-CN bond is cleaved and the reactive amine intermediate readily reacts with th