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First synthesis of 2-[alkylamino(diethoxyphosphoryl)methyl]acrylic ethyl esters

✍ Scribed by Houda Kraı̈em; Meysun Ibrahim Abdullah; Hassen Amri

Book ID
104252690
Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
102 KB
Volume
44
Category
Article
ISSN
0040-4039

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✦ Synopsis

The ethyl a-bromomethyl-b-(diethoxyphosphoryl)acrylic acid ester 9 has been prepared by addition of bromine to allylphosphonate 7 then dehydrobromination with DBU in acetonitrile. Reaction of allylic bromide 9 with primary amines in a bimolecular S N 2%-type mechanism in methanol at low temperature, gives rise to the 2-[alkylamino(diethoxyphosphoryl)methyl]acrylic acid ethyl esters 6.

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