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First Stereospecific Synthesis of (E)- or (Z)-α-Fluoroenones via a Kinetically Controlled Negishi Coupling Reaction.

✍ Scribed by Guillaume Dutheuil; Clotilde Paturel; Xinsheng Lei; Samuel Couve-Bonnaire; Xavier Pannecoucke


Publisher
John Wiley and Sons
Year
2006
Weight
38 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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Stereospecific synthesis of a family of
✍ Fumio Sasaki; Takanori Endo; Masanori Noguchi; Kenji Kawai; Taichi Nakano 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 225 KB 👁 2 views

## Abstract Stereospecific synthesis of a family of novel (__E__)‐2‐aryl‐1‐silylalka‐1,4‐dienes or (__E__)‐4‐aryl‐5‐silylpenta‐1,2,4‐trienes via a cross‐coupling of (__Z__)‐silyl(stannyl)ethenes with allyl halides or propargyl bromide is described. In the reaction with allyl bromide, either a Pd(db