✦ LIBER ✦

First stereoselective synthesis of (1S,2S,4R,5R)-(−)-β-multistriatin

✍ Scribed by Henrichfreise, Peter ;Scharf, Hans-Dieter

Publisher: John Wiley and Sons
Year: 1995
Tongue: English
Weight: 510 KB
Volume: 1995
Category: Article
ISSN: 0947-3440
DOI: 10.1002/jlac.1995199506143

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Starting from 2,3‐O‐(3‐pentylidene)‐D‐glyceraldehyde (3), we prepared the bicyclic pheromone (1__S__,2__S__,4__R__,5__R__)‐(−)‐β‐multistriatin (1) on a gram scale. Key steps of the synthesis are a cis‐selective Wittig olefination followed by diastereo‐selective Michael addition and hydrogenation.

📜 SIMILAR VOLUMES

First Stereoselective Synthesis of (1R,2

First Stereoselective Synthesis of (1R,2R,4R)- and (1S,2R,4S)-2-Substituted-1-azabicyclo[2.2.1]heptanes

✍ Pablo Etayo; Ramón Badorrey; María D. Díaz-de-Villegas; José A. Gálvez 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 248 KB 👁 1 views

An Efficient Stereoselective Synthesis o

An Efficient Stereoselective Synthesis of (2S,4S,5R)-(-)- and (2R,4R,5S)-(+)-Bulgecinine.

✍ Subhash P. Chavan; Cherukupally Praveen; Pallavi Sharma; U. R. Kalkote 📂 Article 📅 2005 🏛 John Wiley and Sons ⚖ 9 KB 👁 1 views

Stereoselective Synthesis of (2R,5R)- an

Stereoselective Synthesis of (2R,5R)- and (2S,5R)-5-Hydroxylysine

✍ Adrianus M. C. H. van den Nieuwendijk; Nicole M. A. J. Kriek; Johannes Brussee; 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 374 KB 👁 1 views

First Stereoselective Total Synthesis of

First Stereoselective Total Synthesis of (-)-(2R,10S)-Megapodiol.

✍ Ramadas Sathunuru; Jean-Charles Quirion 📂 Article 📅 2005 🏛 John Wiley and Sons ⚖ 9 KB 👁 1 views

A Convenient Stereoselective Synthesis o

A Convenient Stereoselective Synthesis of (1R,2S,3R,4S)-3-(Neopentyloxy)isoborneol

✍ Xavier Verdaguer; Iolanda Marchueta; Jordi Tormo; Albert Moyano; Miquel A. Peric 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 German ⚖ 465 KB

## Abstract A convenient preparation of (1__R__,2__S__,3__R__,4__S__)‐3‐(neopentyloxy)isoborneol (= (1__R__,2__S__,3__R__,4__S__)‐3‐(2,2‐dimethyl‐propoxy)‐1,7,7‐trimethylbicyclo[2.2.1]heptan‐2‐ol; 1a), a valuable chiral auxiliary, is described. The synthesis involves six steps starting from the rea

Stéréochimie de (2S, 4S, 5R;2S, 4S, 5S)-

Stéréochimie de (2S, 4S, 5R;2S, 4S, 5S)- et (2R, 4S, 5R;2R, 4S, 5S)-2-alkyl-1,3,4-triméthyl-5-phénylimidazolidines déterminée par RMN-−1H et -−13C

✍ D. Tytgat; M. Gelbcke 📂 Article 📅 2010 🏛 Wiley (John Wiley & Sons) ⚖ 339 KB 👁 1 views

The condensation of (1 R,2S) or (lS,2S)-N,N'-dimethyI-l-phenylpropane-l 2-diamines with aldehydes gives respectively two diastereorneric 2-alkyl-l,3,4-trimethyI-S-phen limidazolidines. At thermodynamical equilibrium the major isomer in the erythro series is this one where t f ! e substituents at pos