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First Solvation Shell of the Cu(II) Aqua Ion: Evidence for Fivefold Coordination

✍ Scribed by Pasquarello, A.

Book ID
120979831
Publisher
American Association for the Advancement of Science
Year
2001
Tongue
English
Weight
221 KB
Volume
291
Category
Article
ISSN
0036-8075

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The isomorphic substitution applied to solutions of NH4PtC14 and NH4PdC14 allows to show the existence of 2 bound water molecules at the apical sites of PtC142-and PdC14\*-ions. The Pt(Pd)-H20 distance results equal to 2.77 A. 0 1998 Elsevier Science B.V.