## Abstract The enantiomers of 3,3,3′,3′‐tetramethyl‐1,1′‐spirobi[3 __H__,2,1]benzoxaselenole have been separated on a chiral preparative chromatographic column. The experimental vibrational circular dichroism (VCD) spectra have been obtained for both enantiomers in CH~2~Cl~2~. The theoretical VCD
First optically active selenurane oxide: Resolution of C2-symmetric 3,3,3′,3′-tetramethyl-1,1′-spirobi [3h,2,1]-benzoxaselenole oxide
✍ Scribed by Józef Drabowicz; Jerzy Luczak; Marian Mikolajczyk; Yohsuke Yamamoto; Shiro Matsukawa; Kin-Ya Akiba
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 109 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0899-0042
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First Synthesis and Structural Determination of 1 , I 'ISpirobis(3H-2,l -benzoxatellurole)-3,3'-dione ([l O=Te-4(C202)])
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## Abstract Several 2‐alkylcarbamato/thiocarbamato/aryloxy/trichloromethyl‐2,3‐dihydro‐5‐propoxy‐1__H__‐1,3,2‐benzodiazaphosphole 2‐oxides (**4** and **6**) were synthesised by reacting 4‐propoxy‐__o__‐phenylenediamine (**1**) with various __N__‐dichlorophosphinyl carbamates (**3**), aryl phosphoro