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First Magnetostructural Study on a Heterodinuclear 2,2′-Bipyrimidine-Bridged Complex

✍ Scribed by Martínez-Lillo, José; Armentano, Donatella; De Munno, Giovanni; Cano, Joan; Lloret, Francesc; Julve, Miguel; Faus, Juan

Book ID
120586543
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
447 KB
Volume
50
Category
Article
ISSN
0020-1669

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A Novel Dinuclear FeII Spin-Crossover Co
A Novel Dinuclear FeII Spin-Crossover Complex Based on a 2,2-Bipyrimidine Bridge Ligand: [Fe(CH3bipy)(NCS)2]2bpym
✍ Ana B. Gaspar; Vadim Ksenofontov; Víctor Martinez; M. Carmen Muñoz; José A. Real 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 157 KB

## Abstract The dinuclear iron(II) complex {[Fe(CH~3~bipy)(NCS)~2~]~2~bpym} has been synthesised and its crystal structure determined at 293 K. The magnetic properties display intramolecular antiferromagnetic coupling at 1 bar (__J__ = −4.2 cm^−1^), and the onset of a pressure‐induced spin conversi