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First Homopolymerizable Monomer Containing [C60]Fullerene as a Monoadduct Substituent

✍ Scribed by Cezar Ungurenasu; Mariana Pinteala

Publisher: John Wiley and Sons
Year: 2005
Tongue: English
Weight: 80 KB
Volume: 26
Category: Article
ISSN: 1022-1336
DOI: 10.1002/marc.200500027

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✦ Synopsis

Abstract

Summary: The hydrosilylation of C~60~ with 2,4,6,8‐tetramethylcyclotetrasiloxane in the presence of platinum/carbon catalyst produced the cationically polymerizable (C~60~HsiMeO)~4~ along with [(C~60~HsiMeO)~3~SiMeO]~2~C~60~H~2~ and a polymer consisting of C~60~ and (SiMeO)~4~ units. The synthesis and characterization of this first polymerizable tetracyclosiloxane ring system containing C~60~ as a monoadduct substituent are also reported.

Synthesis and polymerization of 2,4,6,8‐tetramethyl‐2,4,6,8‐tetrafulleryl‐cyclotetrasiloxane.

imageSynthesis and polymerization of 2,4,6,8‐tetramethyl‐2,4,6,8‐tetrafulleryl‐cyclotetrasiloxane.

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