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First Highly Stereoselective Synthesis of anti-α-Trifluoromethyl-β-amino Acid Derivatives.

✍ Scribed by Taichi Shimada; Masamitsu Yoshioka; Tsutomu Konno; Takashi Ishihara

Publisher
John Wiley and Sons
Year
2007
Weight
26 KB
Volume
38
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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✍ Atsushi Tarui; Kazuyuki Sato; Masaaki Omote; Itsumaro Kumadaki; Akira Ando 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 395 KB 👁 1 views

## Abstract This account concentrates on our new methodologies for the synthesis of fluorine analogues of amino acids and their derivatives using the Reformatsky‐type reactions of ethyl bromodifluoroacetate and ethyl dibromofluoroacetate with imines promoted by the Wilkinson catalyst. First, we pre