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First example of the formation of highly ordered supermolecular structures in a series of gibberellin derivatives

โœ Scribed by A. G. Druganov; V. V. Lapachev; O. P. Petrenko; V. A. Raldugin

Book ID
104851559
Publisher
Springer
Year
1994
Tongue
English
Weight
157 KB
Volume
30
Category
Article
ISSN
0009-3130

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Silyl methylene radical cyclisation of a ~allylic cyclopentannnulated derivative of glucose leads to a single cis fused tricyclie ring system whereas the same cyclisation of the corresponding derivative leads to a mixture of cis and trans fused products. These results can be explained by the prefere