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First Example of a Lewis Acid-Promoted [2 + 1] Cycloaddition of a 1-Thio-2-silylethene

✍ Scribed by Yamazaki, Shoko; Yanase, Yuichiro; Kamimoto, Kyosuke; Yamada, Kuriko; Yamamoto, Kagetoshi


Book ID
126430542
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
64 KB
Volume
66
Category
Article
ISSN
0022-3263

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l-Seleno-2-silylethene 1 undergoes stereoseleetive SnCl,-promoted [2+1] cycloaddition reactions with 2-phosphonoacrylates 2 in high yields; the resulting highly functionalized cyclopropanephosphonic acid ester products 3 are versatile starting materiak for biologically important compounds. 0 1997Els