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First Epoxidation Reaction of Carbonyl Compounds via Ferrocenyl Sulfur Ylides.

✍ Scribed by Stephanie Miniere; Vincent Reboul; Ramon Gomez Arrayas; Patrick Metzner; Juan Carlos Carretero


Publisher
John Wiley and Sons
Year
2004
Weight
176 KB
Volume
35
Category
Article
ISSN
0931-7597

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Reactions of cyclic sulfur ylides with s
✍ Hitoshi Akiyama; Katsuyoshi Ohshima; Tetsuya Fujimoto; Iwao Yamamoto; Ryozo Iriy πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 English βš– 161 KB

## Abstract The reaction of a six‐membered sulfonium ylide **5** with aldehydes or ketones afforded the oxirane derivatives **6a–d** as a mixture of cis and trans isomers in excellent yields. In addition, the same reactions, using five‐ or six‐membered cyclic oxosulfonium ylides **7** and **11**, g