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First Enantioselective Total Synthesis of (8S,12R,15S)-Prostaglandin J2.

โœ Scribed by Giuseppe Zanoni; Alessio Porta; Quintino De Toma; Francesca Castronovo; Giovanni Vidari

Publisher
John Wiley and Sons
Year
2003
Weight
59 KB
Volume
34
Category
Article
ISSN
0931-7597

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85 (12) , 81 (13), 75 (loo), 73 (84). Anal. calc. for CI5H2,O5Si (316.5): C 56.93, H 8.92, Si 8.87; found: C 56.79, H 8.82, Si 8.77. ## (I R.2S.3 S,4S)-I-[ ( tert-Butyl)dimethylsilyloxyjtetrahydro-2,3-(isopropylidenedioxy/-4-f ( Z/-pent-T-enyI]furan ((+)-7). Dropwise, a 15 % (Me,Si),NK soh. in t