First Enantiodivergent Baeyer—Villiger Oxidation by Recombinant Whole-Cells Expressing Two Monooxygenases from Brevibacterium.
✍ Scribed by Marko D. Mihovilovic; Florian Rudroff; Bernhard Mueller; Peter Stanetty
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 128 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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## Abstract In this work the substrate profile and stereoselectivity of engineered whole cells overexpressing the Baeyer–Villiger monooxygenase from __Xanthobacter__ sp. ZL5 with respect to biotransformations of prochiral substrates is characterized. This enzyme catalyzes the desymmetrization of cy