First Direct Observation of Reactive Carbenes in the Cavities of Cation-Exchanged Y Zeolites
β Scribed by Moya-Barrios, Reinaldo; Cozens, Frances L.
- Book ID
- 126818135
- Publisher
- American Chemical Society
- Year
- 2004
- Tongue
- English
- Weight
- 66 KB
- Volume
- 6
- Category
- Article
- ISSN
- 1523-7060
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π SIMILAR VOLUMES
Alkyl-9-Β―uorenyl cations and the parent 9-Β―uorenyl cation are generated via photoheterolysis of the corresponding 9-Β―uorenols within alkali metal zeolites such as LiY, NaY and Nab, and observed directly using nanosecond laser Β―ash photolysis. The observation of the highly reactive and highly unstabl
Ion exchange isotherms at 298 K describing the uni-trivalent exchange of LiY, NaY, KY, RbNaY and CsNaY with Ce 3+ at total normality 0.1 mol equiv. -1 are presented. The out-going cation has a considerable influence on the progress of exchange and the overall preference of the zeolite phase for the