Treatment of benzyl O-/?-n-galactopyranosyl-( 1+3)-2-acetamido-2-deoxy-4,6-O-isopropylidene-j3-D-glucopyranoside with tert-butylchlorodiphenylsiiane afforded the 6'-0-tert-butyldiphenylsilyl ether, which was converted into the 3',4'-0-isopropylidene derivative. Methylation and subsequent removal of
First cyclometalated iridium(III) complex containing methyl 2-amino-2-deoxy-β-d-glucopyranoside as N,O-chelate
✍ Scribed by Marion Graf; Karlheinz Sünkel
- Book ID
- 113642474
- Publisher
- Elsevier Science
- Year
- 2012
- Tongue
- English
- Weight
- 451 KB
- Volume
- 387
- Category
- Article
- ISSN
- 0020-1693
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## Abstract The synthesis of methyl 2‐acetamido‐6‐O‐(N‐methyl‐isonicotinylium)‐2‐deoxy‐β‐D‐glucopyranoside ion (2; iodide and chloride) is reported. Association with hen‐egg‐white lyso zyme causes chemical shift changes for its acetamido and glycosidic methyl groups comparable to those observed for