The 'H and I3C NMR spectra of piperidine and eight monosubstituted piperidines and their spectra with cobalt(II1) mesotetraphenylporphyrin chloride (CoTPPCl) and cobalt(II1) octaethylporphyrin chloride (CoOEPCl) were assigned using a range of NMR techniques. When complexed to the porphyrin shift rea
β¦ LIBER β¦
First Completely Stable Axial Conformers of Monosubstituted Cyclohexanes at Room Temperature
β Scribed by Kang, Fu-An; Yin, Cheng-Lie
- Book ID
- 126398986
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 119 KB
- Volume
- 119
- Category
- Article
- ISSN
- 0002-7863
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~e~~~ a-Chamigren-3-one (+)-8 bearing an axial C1-atom at C(8) exists as a largely dominant conformer with MeeC(5) at the envelope-shaped enone ring pointing away from CI,,-C(8) at the cyclohexane ring ( = B) in the 'normal' chair conformation, as shown by 'H-NMR. In contrast, the a -chamigren-3-ols