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First Chelated Chiral N -Heterocyclic Bis- Carbene Complexes

✍ Scribed by Clyne, Dean S.; Jin, Jian; Genest, Evan; Gallucci, Judith C.; RajanBabu, T. V.

Book ID
126830414
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
62 KB
Volume
2
Category
Article
ISSN
1523-7060

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N-heterocyclic carbenes (NHCs) have found increasing use as reagents for a range of organic transformations and in asymmetric organocatalysis. The performance of these molecules can be improved and tuned by functionalisation. Functionalised carbenes can anchor free carbenes to the metal site, introd