Asymptotic exactness of finite temperatu
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H Narnhofer; W Thirring
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Article
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1981
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Elsevier Science
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English
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By using entropy inequalities with coherent states we prove that for atoms and molecules the partition function of Thomas-Fermi theory becomes exact in the limit Z+ co, in the appropriate scaling. Furthermore the Gibbs state over a suitable algebra converges to a pure state over classical densities