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Fingerprints of Singlet and Triplet Phenyl Cations

โœ Scribed by Micha Slegt; Hermen S. Overkleeft; Gerrit Lodder

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
255 KB
Volume
2007
Category
Article
ISSN
1434-193X

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โœฆ Synopsis

Abstract

The photolyses of seven phenyl cation precursors in acetonitrile in the presence of anisole resulted in four distinct product patterns. These patterns are due to the chemoselective and regioselective chemistry of various phenyl cation isomers. This spinโ€selective chemistry provides a tool with which to fingerprint the singlet/triplet nature of any phenyl cation.(ยฉ Wileyโ€VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

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