β Scribed by S. Daolio; G. Mengoli; M.M. Musiani; P. Bianco
No coin nor oath required. For personal study only.
The anodic oxidation of mercaptoanilina at d&rent metal anodes proves that coherent coatings may be formed in silu on copper only, using the meta isomer. These coatings probably form through the oxidation of an intermediate Cu-3mercaptoaniline complex, which leaves high copper content in the polymer deposit: however, such materials impart outstanding corrosion protection to the substrate. It is suggested that, after easy dimerization of the monomer to disulfide, C-S coupling reactions play a basic role in the constitution of the polymeric network
π SIMILAR VOLUMES
Anodic voltammetric behaviour of anisidines has been studied at the tubular graphite electrade in hydrodynamic conditions. While only one oxidation wave is obtained in the case of ortho and meta isomers, two distinct oxidation waves are obtained in the case of the para-isomer, the total limiting cur