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Film forming reaction at the lithium/electrolyte interface

โœ Scribed by E. Peled

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
947 KB
Volume
9
Category
Article
ISSN
0378-7753

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โœฆ Synopsis

Active metal nonaqueous

systems can be divided into three groups: (a) solid electrolyte interphase (SEI)-free, aqueous-like, active-metal nonaqueous systems, such as aluminium plating baths; (b) metal solvent blue solutions, or solvated electron systems; (c) SE1 battery systems. It is concluded that the only type of system that can be applied in primary and secondary lithium batteries is the SE1 electrode system. The following are presented and discussed: The deposition-dissolution mechanism and the kinetics of SE1 electrodes, the effect of several parameters on the resistivity of the SEI, the growth rate of the SEI, the morphology of the overall passivating layer and the voltage delay problem.

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