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Film-forming ability and mechanical properties of coalesced latex blends

✍ Scribed by S. Lepizzera; C. Lhommeau; G. Dilger; T. Pith; M. Lambla


Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
214 KB
Volume
35
Category
Article
ISSN
0887-6266

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✦ Synopsis


The film-forming ability of latex blends (hard latex / soft latex) and the mechanical behavior at finite strain of latex blend films (soft matrix with tough inclusions) has been investigated. The maximum weight fraction of hard latex particles (f max ) which still gives rise to transparent and crack-free films has been used as filmforming ability criterion. It was shown that when the T g of the soft latex is low ( T g (soft) Γ΅ 0ЊC), f max is constant and equal to 0.55 because the film-forming ability is controlled by contacts between hard particles. Nevertheless, the expected effect of T g (soft) on film-forming ability is observed (i.e., f max decreases when T g (soft) increases) when T g (soft) is above 0ЊC. From the mechanical behavior point of view, it was shown that the two main parameters controlling the mechanical behavior of latex blend films are: the mechanical properties of the soft polymer because it represents the continuous matrix and the weight fraction of hard latex particles since they enhance the local deformation of matrix under load. However, it was also proven that debounding between the high T g latex particles and low T g matrix occurs rapidly (at an elongation ratio Γ‰ 30%) during uniaxial strain experiments and has to be taken into account in order to gain a thorough understanding of the mechanical behavior of these biphasic films.


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