Film-forming ability and mechanical properties of coalesced latex blends
β Scribed by S. Lepizzera; C. Lhommeau; G. Dilger; T. Pith; M. Lambla
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 214 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0887-6266
No coin nor oath required. For personal study only.
β¦ Synopsis
The film-forming ability of latex blends (hard latex / soft latex) and the mechanical behavior at finite strain of latex blend films (soft matrix with tough inclusions) has been investigated. The maximum weight fraction of hard latex particles (f max ) which still gives rise to transparent and crack-free films has been used as filmforming ability criterion. It was shown that when the T g of the soft latex is low ( T g (soft) Γ΅ 0ΠC), f max is constant and equal to 0.55 because the film-forming ability is controlled by contacts between hard particles. Nevertheless, the expected effect of T g (soft) on film-forming ability is observed (i.e., f max decreases when T g (soft) increases) when T g (soft) is above 0ΠC. From the mechanical behavior point of view, it was shown that the two main parameters controlling the mechanical behavior of latex blend films are: the mechanical properties of the soft polymer because it represents the continuous matrix and the weight fraction of hard latex particles since they enhance the local deformation of matrix under load. However, it was also proven that debounding between the high T g latex particles and low T g matrix occurs rapidly (at an elongation ratio Γ 30%) during uniaxial strain experiments and has to be taken into account in order to gain a thorough understanding of the mechanical behavior of these biphasic films.
π SIMILAR VOLUMES
Film-forming polystyrene/poly(n-butyl acrylate-co-glycidyl methacrylate) [PS/P(BA-co-GMA)] core-shell latex particles were prepared via a two-stage emulsion polymerization procedure using a PS latex seed. A delayed addition of GMA was used to locate the functional epoxy groups near the surface of th
Since the synthesis of bulk glassy alloys in multi-component Ln- [1] (Ln: lanthanide metal) and Mg- [2] based alloys by the copper mold casting method in 1989, much effort has been devoted to develop new bulk glassy alloys exhibiting high glass-forming ability (GFA) and useful engineering properties