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Fijianolides, polyketide heterocycles from a marine sponge

✍ Scribed by Quinoa, Emilio; Kakou, Yao; Crews, Phillip

Book ID
121418691
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
395 KB
Volume
53
Category
Article
ISSN
0022-3263

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Total synthesis of mycothiazole, a polyk
Total synthesis of mycothiazole, a polyketide heterocycle from marine sponges
✍ Hideyuki Sugiyama; Fumiaki Yokokawa; Takayuki Shioiri πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 427 KB

Mycothiazole isolated from marine sponges has been efficiently synthesized in a convergent manner. The key reactions involve the thiazole synthesis by dehydrogenation of the thiazolidine with chemical manganese dioxide (CMD), the Stille coupling, and the Nagao asymmetric acetate aldol reaction using