Boron-Based Diastereomerism and Enantiom
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Manfred Braun; Sebastian Schlecht; Marco Engelmann; Walter Frank; Stefan Grimme
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Article
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2008
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John Wiley and Sons
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English
⚖ 301 KB
## Abstract Boron turns out to be a stable stereogenic center in imine complexes of aryl and alkyl boronates. Diastereomerically pure complexes **7a**–**c** are obtained from chiral imine ligands **5a**,**b** that are derived from the amino alcohol (__R__)‐**4**. The configuration at the boron atom