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Fifth-rank molecular polarization tensors

✍ Scribed by L. L. Boyle


Publisher
John Wiley and Sons
Year
1970
Tongue
English
Weight
589 KB
Volume
4
Category
Article
ISSN
0020-7608

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✦ Synopsis


Abstract

Fifth‐rank molecular polarization tensors are discussed in terms of their tensor group which includes both the spatial symmetry and the permutation symmetry of the suffixes. This latter may be described by certain four‐dimensional point groups, which in the nontotally symmetric cases may be projected into three‐dimensional space. The study leads to a determination of the number of independent components of these tensors and a discussion of the types of phenomena which they may be expected to produce.


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A finite field method for calculating spherical tensor molecular polarizability tensors Ξ±(lm;l'm') = βˆ‚Ξ”(lm)/βˆ‚Ο•(l'm')\* by numerical derivatives of induced molecular multipole Ξ”(lm) with respect to gradients of electrostatic potential Ο•(l'm')\* is described for arbitrary multipole ranks l and l'. Int