The work pertains to the application of solid-state luminescence as a characterization tool for glassy ceramic cultural artefacts. An archaeological glass bead collection excavated at the city of Thebes, Greece and considered as unique in terms of typological variety and time span was examined with
Field-assisted solid state doping of glasses for optical materials
β Scribed by A. Quaranta; E. Cattaruzza; F. Gonella; G. Peruzzo; M. Giarola; G. Mariotto
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 311 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0925-3467
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β¦ Synopsis
Field-assisted solid-state ion-exchange (FASSIE) allows the doping of surface glass layers with multivalent ions which could not diffuse into the glass matrix by the usual thermal ion-exchange process in molten salt baths. This paper presents preliminary spectroscopic investigation of the diffusion of chromium in silicate glasses, with the aim at improving the procedures for the production of Cr-doped optical waveguides. Metallic chromium films deposited onto the glass substrates by the rf-sputtering technique were used as metal ions source. The environment of diffused chromium ions into the glass matrix was investigated by means of micro-Raman spectroscopy.
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We present here high-resolution solid state NMR spectra of several oxide and silicate materials that illustrate the improvements obtainable with very high external fields (18.8 and 21.1 T), with probes capable of tuning to a wide frequency range that allow observations of nuclides from high to low m