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Fibrous catalyst for oxidation of hydrogen with oxygen

โœ Scribed by Yu.G. Yegiazarov; V.Z. Radkevich; Jurgen Johann; Helmut Iraushek; V.S. Soldatov


Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
297 KB
Volume
44
Category
Article
ISSN
1381-5148

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Methylrhenium trioxide as a catalyst for
โœ Zuolin Zhu; James H. Espenson ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 643 KB

Metbylrhenium trioxide (MTO) was found to be a good catalyst for the oxidation of tertiary phospbines by molecular oxygen at room temperature. Evidence is given that an intermediate Re( V) compound -CH3Re0,, or the adduct CH,ReO, . O=PPh,is involved. The deoxygenation of epoxides, sulfoxides, N-oxid