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Fibre-optic sensor for the determination of carboxylic acids based on fluorescence enhancement of lipophilized fluorescein isologues

✍ Scribed by Hui-Hui Zeng; Ke-Min Wang; Xiao-Hai Yang; Ru-Qin Yu


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
521 KB
Volume
287
Category
Article
ISSN
0003-2670

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✦ Synopsis


A fibre-optic sensor for the determination of carboxyhc acids based on fluorescence enhancement of lipophilized fluorescein isologues dissolved in a plasticized polyfvinyl chloride1 membrane was developed. With the optimum conditions described, carboxylic acids in sample solutions from 1 to 9 M (formic acid), 0.5 to 10 M (acetic acid), 0.1 to 2.7 M (propionic acid) and 1 X 10m4 to 1 X lo-* M (benzoic acid) can be determined. The response times of the sensor to carboxylic acid are less than 1.5 min. In addition to high reproducibility of the fluorescence signal, the sensor exhibits fair selectivity for carboxylic acids.