Fibers from cellulose solutions in mixtures of dimethylformamide or ethyl acetate with nitrogen tetroxide

Kinetics and mechanism of the reactions

Kinetics and mechanism of the reactions of the superoxide ion in solutions. III. Kinetics and mechanism of the reaction of the superoxide ion with ethyl acetate in dimethylformamide, acetonitrile, and their mixtures

✍ I. B. Afanas′ev; N. S. Kuprianova 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 English ⚖ 237 KB

## Abstract The kinetics of the reaction of the superoxide ion with ethyl acetate have been studied in DMF, AN, and their mixtures. It was shown that the rate constants depend on the ethyl acetate concentration, which indicates the formation of an intermediate in this process. Equilibrium constants