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Ferromagnetic intermolecular interaction of organic radical, galvinoxyl

โœ Scribed by Awaga, K.; Sugano, T.; Kinoshita, M.

Book ID
122750557
Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
328 KB
Volume
27
Category
Article
ISSN
0379-6779

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๐Ÿ“œ SIMILAR VOLUMES

Ferromagnetic intermolecular interaction
Ferromagnetic intermolecular interaction in the galvinoxyl radical: Cooperation of spin polarization and charge-transfer interaction
โœ Kunio Awaga; Tadashi Sugano; Minoru Kinoshita ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 423 KB

The orbital energies and the intermolecular overlap integrals of the galvinoxyl radical are calculated. It is found that the ferromagnetic intermolecular interaction in galvinoxyl can be qualitatively interpreted by a combined effect of spin polarization within the radical and charge-transfer intera

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X-ray crystal analysis and magnetic measurements reveal the ferromagnetic linear chain with JF/kB=0.27 K in an a-nitronyl nitroxide, 2-(4-pyridyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-1 -oxyl 3-N-oxide.