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Femtosecond transient absorption study of the ring-opening reaction of 1,3-cyclohexadiene

✍ Scribed by Stuart Pullen; Larry A. Walker II; Brent Donovan; Roseanne J. Sension


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
449 KB
Volume
242
Category
Article
ISSN
0009-2614

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Ultrafast dynamics of photoexcited trans
✍ Kaoru Ohta; Yukito Naitoh; Kenichi Saitow; Keisuke Tominaga; Noboru Hirota; Keit πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 English βš– 453 KB

We have investigated the ultrafast dynamics of trans-1,3,5-hexatriene in cyclohexane and acetonitrile solutions following photoexcitation to the 1 1B u state. The transient absorption in the visible region consists of an instantaneous rise (< 150 fs) and decay in less than 500 fs, whose time constan