We have investigated the ultrafast dynamics of trans-1,3,5-hexatriene in cyclohexane and acetonitrile solutions following photoexcitation to the 1 1B u state. The transient absorption in the visible region consists of an instantaneous rise (< 150 fs) and decay in less than 500 fs, whose time constan
โฆ LIBER โฆ
Femtosecond Transient Absorption Studies of trans - and cis -1,3,5-Hexatriene in Solution
โ Scribed by Ohta, Kaoru; Naitoh, Yukito; Tominaga, Keisuke; Hirota, Noboru; Yoshihara, Keitaro
- Book ID
- 126184870
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 261 KB
- Volume
- 102
- Category
- Article
- ISSN
- 1089-5639
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Two-photon absorption spectra of trans-and cis-1,3,5-hexatriene in the liquid state have beet ob:erved in the frequency range of 20 = 3oooO-SO000 cm-t, by analyzing the interference effe& of Raman and two-photon resonances in the CARS and CSRS lineshape. In both isomers, a broad two-photon absorptio