Femtosecond Transient Absorption Anisotropy Study on [Ru(bpy) 3 ] 2 + and [Ru(bpy)(py) 4 ] 2 + . Ultrafast Interligand Randomization of the MLCT State
✍ Scribed by Wallin, S.; Davidsson, J.; Modin, J.; Hammarström, L.
- Book ID
- 125981439
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 10 KB
- Volume
- 109
- Category
- Article
- ISSN
- 1089-5639
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## Abstract A novel ligand 3‐(1__H__‐imidazo[4,5‐__f__][1,10]phenanthrolin‐2‐yl)‐4__H__‐1‐benzopyran‐4‐one (ipbp) and its ruthenium(II) complexes [Ru(bpy)~2~(ipbp)]^2+^ (**1**) and [Ru(ipbp)(phen)~2~]^2+^ (**2**) (bpy=2,2′‐bipyridine, phen=1,10‐phenanthroline) were synthesized and characterized by
## Abstract The new ligand bdip (=2‐(1,3‐benzodioxol‐4‐yl)‐1__H__‐imidazo[4,5‐__f__][1,10]phenanthroline) and its Ru^II^ complexes [Ru(4,7‐dmp)~2~(bdip)]^2+^ (**1**; 4,7‐dmp=4,7‐dimethyl‐1,10‐phenanthroline) and [Ru(bpy)~2~(bdip)]^2+^ (**2**; bpy=2,2′‐bipyridine) were synthesized and characterized