✦ LIBER ✦

Femtosecond photoassociation spectroscopy: coherent bond formation

✍ Scribed by Una Marvet; Marcos Dantus

Publisher: Elsevier Science
Year: 1995
Tongue: English
Weight: 483 KB
Volume: 245
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(95)01018-5

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✦ Synopsis

The method femtosecond photoassociation spectroscopy (FPAS) is introduced and we report on its application to the study of the reaction Hg + Hg + hv ~ Hg 2. Our results demonstrate coherent bond formation obtained in the femtosecond time scale from free unbound reactants. The product Hg 2 is formed in the D1 u state and shows a high degree of rotational anisotropy induced by the polarization of the binding femtosecond pulse.

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